Blends of certain polyesters with acrylics

ABSTRACT

This invention relates to a blend comprising: (A) an aliphatic or cycloaliphatic polyester or copolyester and (B) an acrylic polymer or copolymer.

FIELD OF THE INVENTION

This invention relates to clear, immiscible blends of certain aliphatic or cycloaliphatic polyesters with acrylic polymers or copolymers.

BACKGROUND OF THE INVENTION

The vast majority of two-phase polymer blends form articles which are visually opaque and thus, cannot be used in applications requiring clarity. It is unusual to find blends of two polymers which form two-phase materials in the solid state and which are also visually clear.

Refractive indices of polymers vary over a broad range. For instance, many polymers have refractive indices in the range of 1.35 to 1.65. It is exceptional to find a pair of polymers where the refractive index difference is similar so that visually clear blends of the two immiscible components are formed.

It is known that the matching of refractive indices of polymer pairs can result in visually clear articles of the blends of the two polymers. L. Bohn, Polymer Handbook, 2nd ed., pp. 111-211, Wiley Interscience, New York ((1975); J. MacKnight et al., Polymer Blends, Vol. I, p. 185, Academic Press, New York (1978). Biangardi et al., Die Angew. Makromole. Chemie, 183, 221 (1990), have developed model calculations which quantify this phenomena and evaluate the light scattering of certain blends as a function of particle diameter, refractive index, wavelength, and particle structure.

Bauer et al., Adv. Chem. Ser., 99, 251 (1971), report transparent blends which were prepared from poly(methyl methacrylate) and diene elastomers. Skochdopole et al., et al., Polym. Engr. Sci., 27, 627 (1987), reported a blend of polycarbonate and styrene-acrylonitrile which was transparent due to a near match of the refractive indices of the two materials. Tse et al., J. Appl. Polym. Sci., 42, 1205 (1991), disclosed blends of poly(vinyl chloride) and chlorinated polyethylene which were translucent due to a close match of refractive indicies.

Clear composites have been reported also. See Breuer and Grzesitza, Die Angew. Makromol. Chemie, 45, 1 (1975). U.S. Pat. No. 4,581,288 (1986) disclosed lens materials which were composites of glass and plastic with refractive indices matched to ±0.0020. U.S. Pat. No. 3,441,525 [1969] disclosed glass composites based on diallylic phthalate polymers where the refractive indices were sufficiently matched to yield clear materials. Linet al., Polym. Engr. Sci., 37, 344 (1992) reported the preparation of transparent poly(methyl methacrylate) composites by matching the refractive index of the glass fiber reinforcement to the refractive index of the poly(methyl methacrylate) matrix.

There is a need in the art for visually clear, two-phase blends which are particularly useful in applications requiring tough weather resistant material.

SUMMARY OF THE INVENTION

This invention relates to clear blends of aliphatic or cycloaliphatic polyesters with acrylic polymers.

More particularly this invention relates to a composition which is a visually clear, two-phase blend of thermoplastic polymers comprising:

(A) from 99% to 1% by weight of an aliphatic or cycloaliphatic polyester or copolyester and

(B) from 1% to 99% by weight of an acrylic polymer or copolymer, wherein an article prepared from said blend has a diffuse transmittance value of 40% or greater as determined by ASTM Method D1003.

The absolute value of the difference in refractive indices for Components (A) and (B) of the invention is less than about 0.008.

Visually clear, immiscible blends of acrylic polymers with aliphatic polyesters are not believed to have been disclosed in the prior art.

DETAILED DESCRIPTION OF THE INVENTION

The composition of the invention is a visually clear blend of thermoplastic polymers comprising:

(A) from 99% to 1, preferably 85 to 20, more preferably 80 to 20, even more preferably 60 to 40 percent by weight of an aliphatic or cycloaliphatic polyester or copolyester and

(B) from 1% to 99, preferably 15 to 80, more preferably 20 to 80 percent, even more preferably 40 to 60 percent by weight of an acrylic polymer or copolymer, wherein an article prepared from said blend has a diffuse transmittance value of 40% or greater as determined by ASTM Method D1003.

The aliphatic or cycloaliphatic polyester or copolyester of Component (A) comprises:

(1) an acid (or equivalent ester) portion selected from the group of aliphatic and cycloaliphatic acids comprising at least one of the following acids:

oxalic acid

malonic acid

succinic acid

glutaric acid

adipic acid

pimelic acid

suberic acid

azelaic acid

sebacic acid

cis- or trans-1,4-cyclohexanedicarboxylic acid

and

(2) a glycol portion selected from the group of aliphatic and cycloaliphatic glycols comprising at least one of the following glycols

ethylene glycol

1,3-trimethylene glycol

1,4-butanediol

1,5-pentanediol

1,6-hexanediol

1,7-heptanediol

1,8-octanediol

1,9-nonanediol

neopentyl glycol

cis- and trans cyclohexanedimethanol

cis- and trans-2,2,4,4-tetramethyl-1,3-cyclobutanediol

diethylene glycol

Aromatic acids and glycols may also be added, depending on the overall composition of the aliphatic or cycloaliphatic polyester, and the composition of the acrylic with which it is being blended. These polyesters may be prepared by methods well known in the art, for example, methods similar to those described in U.S. Pat. Nos. 2,647,885; 2,643,989; 2,534,028; 2,578,660; 2,742,494; and 2,901,466.

The inherent viscosity of the aliphatic or cycloaliphatic polyester or copolyester is preferably, at least 0.3 dL/g, and more preferably, 0.5 dL/g or more.

The acrylic polymer is comprised of monomers or mixtures of monomers including, but not limited to:

methyl acrylate

methyl methacrylate

ethyl acrylate

ethyl methacrylate

butyl acrylate

butyl methacrylate

cyclohexylacrylate

cyclohexylmethacrylate

styrene

methylstyrene

and other monomers known to function in a similar manner to any of the monomers listed above. These acrylic polymers may be prepared by methods which are well known in the art. See Encyclopedia of Polymer Science and Technology, John Wiley & Sons (1985).

The inherent viscosity of the acrylic polymer or copolymer is preferably 0.2 dL/g and more preferably, 0.4 dL/g, or more.

It is preferable that articles prepared from the blends of the invention are visually clear having a diffuse transmittance value of greater than about 60% or more preferably, greater than 80%, as determined by ASTM Method D1003.

Component (A) is preferably a polyester prepared by the reaction of: (1) trans-1,4-cyclohexanedicarboxylic acid for the acid portion and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol for the diol or glycol portion, (2) trans-1,4-cyclohexane-dicarboxylic acid for the acid portion and diethylene glycol for the diol or glycol portion, (3) trans-1,4-cyclohexanedicarboxylic acid for the acid portion and neopentyl glycol for the diol or glycol portion, (4) adipic acid for the acid portion and 1,4-cyclohexanedimethanol for the diol or glycol portion, (5) adipic acid and sebacic acid for the acid portion and 1,4-cyclohexanedimethanol for the diol or glycol portion, (6) a mixture of trans-1,4-cyclohexanedicarboxylic acid and cis-1,4-cyclohexanedicarboxylic acid for the acid portion and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol for the diol or glycol portion.

It is preferred that Component (B) comprises methyl methacrylate), cyclohexylmethacrylate, methyl acrylate, butyl acrylate and styrene or blends thereof. Methyl methacrylate and cyclohexylmethacrylate are preferred.

The following blends are particularly preferred within the scope of this invention:

(1) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 90-50 mole %, preferably 80-60 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 10-50 mole %, preferably 20-40 mole % of 1,4-cyclohexanedimethanol; and

(B) poly(methyl methacrylate);

(2) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-1 mole %; preferably 30-10 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 60-99 mole %; preferably 70-90 mole % of 1,4-cyclohexanedimethanol; and

(B) Poly(cyclohexylmethacrylate);

(3) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and a glycol selected from the group consisting of neopentyl glycol and diethylene glycol; and

(B) poly(methyl methacrylate);

(4) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-60 mole % 1,6-hexanediol and 60-40 mole % 1,8-octanediol; and

(B) poly(methyl methacrylate);

(5) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and

(B) poly(methyl methacrylate);

(6) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and

(B) poly(methyl methacrylate) and methyl acrylate;

(7) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and

(B) 65-85 mole % methyl acrylate and 35-15 mole % cyclohexylmethacrylate; and

(8) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and

(B) 65-85 mole %, preferably 70-80 mole %, methyl acrylate and 35-15 mole %, preferably 30-20 mole %, cyclohexylmethacrylate.

In general, in order to obtain a visually clear, immiscible blend of the aliphatic or cycloaliphatic polyester and acrylic polymer, the refractive indices of the two polymers should not differ by an absolute value of more than about 0.008, preferably 0,006, more preferably 0.004, or lower. However, the maximum difference in refractive index which may be tolerated depends on the blend composition, particle diameter, refractive index, wavelength, and particle structure as described by Biangardi et al., Die Angew. Makromole. Chemie, 183, 221 (1990).

The aliphatic polyester may be a homopolymer of one acid and one glycol or a copolymer of one or more acids and/or one or more glycols. The acrylic polymer may be a homopolymer or a copolymer of two or more acrylic monomers.

These blends may be prepared by any method known in the art. These blends may be compounded in the melt, for example, by using a single screw or twin screw extruder. They may also be prepared by blending in solution. Additional components such as stabilizers, flame retardants, colorants, lubricants, release agents, impact modifiers, and the like may also be incorporated into the formulation.

These blends are useful as thermoplastic molding compositions.

Whenever the term "inherent viscosity" (I.V.) is used in this application, it will be understood to refer to viscosity determinations made at 25° C. using 0.5 grams of polymer per 100 ml of a solvent comprising 60 weight phenol and 40 weight % tetrachloroethane.

The term "absolute value" as used herein is defined as the mathematical term relating to real numbers where the absolute value is the value irrespective of sign. The term "absolute value" as referred to herein relates to differences in refractive indices of two polymers.

A "visually clear" blend is defined herein as one where the article made therefrom has a diffuse transmittance value of about 40% or greater. An "opaque" or "cloudy" blend is defined as one where the article made therefrom has a diffuse transmittance value of less than about 40%.

The diffuse transmittance of the injection molded articles formed from the blends of the invention is determined by ASTM Method D1003.

This invention can be further illustrated by the following examples of preferred embodiments thereof, although it will be understood that these examples are included merely for purposes of illustration and are not intended to limit the scope of the invention unless otherwise specifically indicated.

EXAMPLES

In the following examples, refractive indices were measured on polymer films using a refractometer.

Example 1

Blends of aliphatic polyesters with a commercial poly(methyl methacrylate) were prepared and analyzed for clarity. The composition of the blends was 50% by weight aliphatic polyester and 50% by weight poly(methyl methacrylate). The blends were prepared in methylene chloride solution and then precipitated into methanol. The precipitate was collected and dried overnight under vacuum at 50° C. The samples were then compression molded at 200° C. into plaques 0.125 inches thick.

The poly(methyl methacrylate) used was Acrylite H12, obtained from Cyro Industries of Mount Arlington, N.J. Its measured refractive index was 1.491.

Four copolyesters were prepared by polymerization in the melt. The compositions of the polyesters along with the measured refractive indices are given in Table 1.1.

                  TABLE 1.1                                                        ______________________________________                                         Polyesters of Example 1                                                                                           Measured                                    Example                            Refractive                                  #      Acid Portion  Glycol Portion                                                                               Index                                       ______________________________________                                         A      trans-1,4-cyclo-                                                                             80 mol % 2,2,4,4-                                                                            1.493                                              hexanedicarboxylic                                                                           tetramethyl-1,3-                                                 acid          cyclobutanediol                                                                20 mol % 1,4-cyclo-                                                            hexanedimethanol                                          1B     trans-1,4-cyclo-                                                                             60 mol % 2,2,4,4-                                                                            1.497                                              hexanedicarboxylic                                                                           tetramethyl-1,3-                                                 acid          cyclobutanediol                                                                40 mol % 1,4-cyclo-                                                            hexanedimethanol                                          1C     trans-1,4-cyclo-                                                                             30 mol % 2,2,4,4-                                                                            1.503                                              hexanedicarboxylic                                                                           tetramethyl-1,3-                                                 acid          cyclobutanediol                                                                70 mol % 1,4-cyclo-                                                            hexanedimethanol                                          1D     trans-1,4-cyclo-                                                                             10 mol % 2,2,4,4-                                                                            1.507                                              hexanedicarboxylic                                                                           tetramethyl-1,3-                                                 acid          cyclobutanediol                                                                90 mol % 1,4-cyclo-                                                            hexanedimethanol                                          ______________________________________                                    

The aliphatic polyesters may be prepared by techniques well known in the art. The clarity of the blends which were compression molded into plaques is shown in Table 1.2. Scanning electron microscopy and transmission electron microscopy of the blends confirmed that two polymeric phases were present.

                  TABLE 1.2                                                        ______________________________________                                         Clarity of the blends of Example 1 in                                          Compression Molded Plaques                                                     Example                Difference in                                           #           Blend Clarity                                                                             Refractive Indices                                      ______________________________________                                         1A          Clear      0.002                                                   1B          Clear      0.006                                                   1C          Cloudy     0.012                                                   1D          Cloudy     0.016                                                   ______________________________________                                    

This example illustrates blends of aliphatic polyesters and poly(methyl methacrylate) which were visually clear or cloudy depending on the difference in refractive index between the components. The blends in which the refractive index difference was less than about 0.008 were visually clear while those in which the refractive index difference was greater than about 0.008 were cloudy. Additionally, this example illustrates the importance of the polyester composition in obtaining a visually clear blend.

Example 2

Blends of aliphatic polyesters with a poly(cyclohexyl methacrylate) were prepared and analyzed for clarity. The composition of the blends was 50% by weight aliphatic polyester and 50% by weight poly(cyclohexylmethacrylate). The blends were prepared in methylene chloride solution and then precipitated into methanol. The precipitate was collected and dried overnight under vacuum at 50° C. The samples were then compression molded at 200° C. into plaques 0.125 inches thick.

The poly(cyclohexylmethacrylate) used was purchased from Polysciences of Niles, Ill. Its measured refractive index was 1,507.

Four copolyesters, 2A-2D, were prepared by polymerization in the melt. These were the same polyesters used in Example 1 as 1A-D, respectively. The composition of the polyesters along with the measured refractive indices are given in Table 1.1.

The clarity of the blends which were compression molded into plaques is shown in Table 2.1. Scanning electron microscopy and transmission electron microscopy of the blends confirmed that two polymeric phases were present.

                  TABLE 2.1                                                        ______________________________________                                         Clarity of the blends of Example 2 in                                          Compression Molded Plaques                                                     Example                Difference in                                           #           Blend Clarity                                                                             Refractive Indices                                      ______________________________________                                         2A          Cloudy     0.014                                                   2B          Cloudy     0.010                                                   2C          Clear      0.004                                                   2D          Clear      0.000                                                   ______________________________________                                    

This example illustrates blends of polyesters and poly(cyclohexylmethacrylate) which were visually clear or cloudy depending on the difference in refractive index between the components. The blends in which the refractive index difference was less than about 0.008 were visually clear while those in which the refractive index difference was greater than about 0.008 were cloudy. Additionally, this example illustrates the importance of the polyester composition in obtaining a visually clear blend. Comparison of Examples 1 and 2 demonstrates the importance of the composition of the acrylic in obtaining a visually clear blend.

Example 3

Blends of various polyesters with a commercial poly(methyl methacrylate) were prepared and analyzed for clarity. The composition of the blends was 80% by weight poly(methyl methacrylate) and 20% by weight polyester. The blends were prepared in methylene chloride solution and then precipitated into methanol. The precipitate was collected and dried overnight under vacuum at 50° C. The samples were then compression molded at 200° C. into plaques 0.125 inches thick.

The poly(methyl methacrylate) used was Acrylite H12, obtained from Cyro Industries of Mount Arlington, N.J. Its measured refractive index was 1.491.

The polyesters and copolyesters were prepared by polymerization in the melt. The polyesters may be prepared by techniques well known in the art. The composition of the polyesters along with the observed clarity of the blends are given in Table 3.1.

                  TABLE 3.1                                                        ______________________________________                                         Clarity of Blends of Polyesters with                                           Poly(methyl methacrylate) for Example 3.                                                                           Visual                                     Exam-                               Appear-                                    ple # Acid Portion   Glycol Portion ance                                       ______________________________________                                         3A    trans-1,4-cyclo-                                                                              hydroquinone   Opaque                                           hexanedicarboxylic                                                             acid                                                                     3B    trans-1,4-cyclo-                                                                              ethylene glycol                                                                               Opaque                                           hexanedicarboxylic                                                             acid                                                                     3C    trans-1,4-cyclo-                                                                              diethylene glycol                                                                             Clear                                            hexanedicarboxylic                                                             acid                                                                     3D    trans-1,4-cyclo-                                                                              50 mol % 1,6-hexane-                                                                          Clear                                            hexanedicarboxylic                                                                            diol                                                            acid           50 mol % 1,8-octane-                                                           diol                                                      3E    trans-1,4-cyclo-                                                                              neopentyl glycol                                                                              Clear                                            hexanedicarboxylic                                                             acid                                                                     3F    50 mol % terephthalic                                                                         neopentyl glycol                                                                              Opaque                                           acid                                                                           50 mol % isophthalic                                                           acid                                                                     3G    adipic acid    1,4-cyclohexane-                                                                              Clear                                                           dimethanol                                                3H    50 mol % adipic acid                                                                          1,4-cyclohexane-                                                                              Clear                                            50 mol % sebacic acid                                                                         dimethanol                                                3I    50 mol % terephthalic                                                                         1,4-cyclohexane-                                                                              Opaque                                           acid           dimethanol                                                      50 mol % isophthalic                                                           acid                                                                     ______________________________________                                    

Examples 3A through 3E show the results for blends where the polyester was prepared from trans-1,4-cyclo-hexanedicarboxylic acid. The fact that some blends are clear and some are opaque demonstrates the importance of proper selection of the glycol in order to obtain a visually clear blend. In Examples 3E and 3F both of the polyesters were prepared from neopentyl glycol. However, only Example 3E is a clear blend. This example also demonstrates the importance of selecting the proper acid. A similar observation may be made when considering Examples 3G through 3I.

Example 4--Counter Example

Blends of aromatic polyesters with a commercial poly(methyl methacrylate) were prepared and analyzed for clarity. The composition of the blends was 75% by weight polyester and 25% by weight poly(methyl methacrylate). The blends were prepared by mixing in the melt using a Werner and Pfleiderer 28 mm twin screw extruder. The blends were then injection molded using a Toyo 90 injection molding machine into plaques 0.125 inches thick. The melt temperatures used during processing were between 260° C. and 300° C.

The poly(methyl methacrylate) used was Acrylite H12, obtained from Cyro Industries of Mount Arlington, N.J. Its measured refractive index was 1,491.

Five polyesters and copolyesters were prepared by polymerization in the melt. The composition of the polyesters along with the measured refractive indices are given in Table 4.1.

    ______________________________________                                         4.1 Polyesters of Example 4.                                                                                      Measured                                    Example                            Refractive                                  #      Acid Portion Glycol Portion Index                                       ______________________________________                                         4A     terephthalic acid                                                                           100 mol % ethylene                                                                            1.575                                                           glycol                                                     4B     terephthalic acid                                                                           69 mol % ethylene                                                                             1.568                                                           glycol                                                                         31 mol % 1,4-cyclo-                                                            hexanedimethanol                                           4C     terephthalic acid                                                                           45 mol % ethylene                                                                             1.562                                                           glycol                                                                         55 mol % 1,4-cyclo-                                                            hexanedimethanol                                           4D     terephthalic acid                                                                           19 mol % ethylene                                                                             1.556                                                           glycol                                                                         81 mol % 1,4-cyclo-                                                            hexanedimethanol                                           4E     terephthalic acid                                                                           100 mol % 1,4-cyclo-                                                                          1.552                                                           hexanedimethanol                                           ______________________________________                                    

The polyesters were prepared by techniques well known in the art. The clarity of the blends which were injection molded into plaques is shown in Table 4.2.

                  TABLE 4.2                                                        ______________________________________                                         Clarity of the blends of Example 4 in                                          Injection Molded Plaques                                                       Example                Difference in                                           #           Blend Clarity                                                                             Refractive Indices                                      ______________________________________                                         4A          Opaque     0.084                                                   4B          Opaque     0.077                                                   4C          Opaque     0.071                                                   4D          Opaque     0.065                                                   4E          Opaque     0.061                                                   ______________________________________                                    

This example illustrates several cases where blends of polyesters with an acrylic are opaque materials. In all of these blends there was a large refractive index difference between the components and the blends were observed to be opaque. Comparison with Examples 1 and 3 illustrate the importance of proper selection of the polyester in order to obtain a visually clear blend.

Example 5

Blends of various acrylics with a polyester were prepared and characterized. The polyester used was prepared from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and a mixture of 50 mol % trans-1,4-cyclohexanedicarboxylic acid and 50 mol % cis-1,4-cyclohexane-dicarboxylic acid. This polyester was prepared by polymerization in the melt. The refractive index of the polyester was measured at 1.488. The composition of the blends was 80% by weight polyester and 20% by weight acrylic. The blends were prepared in methylene chloride solution and then precipitated into methanol. The precipitate was collected and dried overnight under vacuum at 50° C. The samples were then compression molded at 200° C. into plaques 0.125 inches thick.

The acrylic copolymers were prepared using a mixture of monomers. The acrylic composition along with observations of the blend clarity are presented in Table 5.1

                  TABLE 5.1                                                        ______________________________________                                         Clarity of Blends of Various Acrylics with                                     a Particular Polyester for Example 5                                           Example                      Blend                                             #       Monomer Composition  Appearance                                        ______________________________________                                         5A      100 mol % methyl methacrylate                                                                       Clear                                             5B      80 mol % methyl methacrylate                                                                        Clear                                                     20 mol % methyl acrylate                                               5C      100 mol % cyclohexylmethacrylate                                                                    Opaque                                            5D      75 mol % methyl acrylate                                                                            Clear                                                     25 mol % cyclohexylmethacrylate                                        5E      100 mol % styrene    Opaque                                            5F      80 mol % butyl acrylate                                                                             Clear                                                     20 mol % styrene                                                       ______________________________________                                    

Examples 5A shows the result for a clear blend with poly(methyl methacrylate). The addition of a small amount of methyl acrylate comonomer in Example 5B results in an acrylic polymer which still forms a clear blend with the polyester. Example 5C shows a visually opaque blend of the polyester with poly(cyclohexylmethacrylate). However, Example 5D demonstrates that the addition of a significant amount of another comonomer to the acrylic then results in a blend that is clear.

The fact that some blends are clear and some are opaque demonstrates the importance of proper selection of the acrylic polymer. This Example further demonstrates that a wide range of different acrylics may form visually clear blends with a particular polyester.

The invention has been described in detail with particular reference to preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention. Moreover, all patents, patent applications (published and unpublished, foreign or domestic), literature references or other publications noted above are incorporated herein by reference for any disclosure pertinent to the practice of this invention. 

I claim:
 1. A two-phase blend comprising:(A) from 99% to 1% by weight of cycloaliphatic polyester or copolyester, and (B) from 1% to 99% by weight of an acrylic polymer or copolymer, wherein components (A) and (B) of said blend are selected from one of the following combinations: (1) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 90-50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 10-50 mole % of 1,4-cyclohexanedimethanol; and(B) poly(methyl methacrylate); (2) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-1 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 60-99 mole % of 1,4-cyclohexanedimethanol; and(B) poly(cyclohexylmethacrylate); (3) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and a glycol selected from the group consisting of neopentyl glycol and ethylene glycol; and(B) poly(methyl methacrylate); (4) (A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-60 mole % 1,6-hexanediol and 60-40 mole % 1,8-octanediol; and(B) poly(methyl methacrylate); (5) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and(B) poly(methyl methacrylate); (6) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and(B) poly(methyl methacrylate) and methyl acrylate; (7) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and(B) 65-85 mole % methyl acrylate and 35-15 mole % cyclohexyl methacrylate; and (8) (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and(B) 70-90 mole % butyl acrylate and 30-10 mole % styrene, and further wherein an article prepared from said blend is visually clear having a diffuse transmittance value of 40% or greater as determined by ASTM Method D1003.
 2. A blend according to claim 1 comprising:(A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 90-50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 10-50 mole % of 1,4-cyclohexanedimethanol; and (B) poly(methyl methacrylate).
 3. A blend according to claim 1 comprising:(A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-1 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 60-99 mole % of 1,4-cyclohexanedimethanol; and (B) poly(cyclohexylmethacrylate).
 4. A blend according to claim 1 comprising:(A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and a glycol selected from the group consisting of neopentyl glycol and ethylene glycol; and (B) poly(methyl methacrylate).
 5. A blend according to claim 1 comprising:(A) a polyester consisting of 1,4-cyclohexanedicarboxylic acid and 40-60 mole % 1,6-hexanediol and 60-40 mole % 1,8-octanediol; and (B) poly(methyl methacrylate).
 6. A blend according to claim 1 comprising:(A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) poly(methyl methacrylate).
 7. A blend according to claim 1 comprising: (A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and(B) poly(methyl methacrylate) and methyl acrylate.
 8. A blend according to claim 1 comprising:(A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 65-85 mole % methyl acrylate and 35-15 mole % cyclohexylmethacrylate.
 9. A blend according to claim 1 comprising:(A) a polyester consisting of 40-60 mole % trans-1,4-cyclohexanedicarboxylic acid and 60-40 mole % cis-1,4-cyclohexanedicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol; and (B) 70-90 mole % butyl acrylate and 30-10 mole % styrene.
 10. The blend according to claim 1 wherein Component (A) is present in the amount of 85% to 20% by weight and Component (B) is present in the amount of 15% to 80% by weight.
 11. The blend according to claim 10 wherein Component (A) is present in the amount of 60% to 40% by weight and Component (B) is present in the amount of 40% to 60% by weight.
 12. The blend according to claim 1 wherein said absolute value of the difference in refractive indices for Components (A) and (B) is 0.006 or less.
 13. The blend according to claim 12 wherein the absolute value of the difference in refractive indices for Components (A) and (B) is less than about 0.008.
 14. A thermoplastic molding composition comprising the blend according to claim
 1. 